The 1:1 charge-transfer complex dibenzotetrathiafulvalene-pyromellitic dianhydride (DBTTF-PMDA)

被引：3
|
作者：
Payne, Margaret E. [1 ]
Goetz, Katelyn P. [1 ]
Day, Cynthia S. [2 ]
Jurchescu, Oana D. [1 ]
机构：
[1] Wake Forest Univ, Dept Phys, Winston Salem, NC 27109 USA
[2] Wake Forest Univ, Dept Chem, Winston Salem, NC 27109 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2014年 / 70卷
基金：
美国国家科学基金会;
关键词：
D O I：
10.1107/S1600536814013324
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title charge-transfer (CT) complex, C10H2O6 center dot C14H8S4, composed of donor dibenzotetrathiafulvalene (DBTTF) and acceptor pyromellitic dianhydride (PMDA), forms a mixed stacking pattern along the [110] direction. The constituent molecules occupy crystallographic inversion centers. They are nearly parallel and lie ca. 3.41 angstrom from each other. The crystals exhibit a high degree of donor/acceptor overlap [88.20 (4)%] in the long direction of the DBTTF and PMDA molecules as compared with 51.27 (5)% in the shortest direction of the molecules.
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页码：O844 / +
页数：9
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