ELECTROCHEMICAL INCORPORATION OF CARBON-DIOXIDE INTO ALKENES BY NICKEL-COMPLEXES

被引：72
|
作者：
DERIEN, S
CLINET, JC
DUNACH, E
PERICHON, J
机构：
[1] CNRS,ELECTROCHIM CATALYSE & SYNTHESE ORGAN LAB,UMR 28,F-94320 THIAIS,FRANCE
[2] UNIV PARIS 11,INST CHIM MOLEC ORSAY,F-91405 ORSAY,FRANCE
来源：
TETRAHEDRON | 1992年 / 48卷 / 25期
关键词：
D O I：
10.1016/S0040-4020(01)89021-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Electrogenerated Ni(0) complexes from stable Ni(II) compounds are the catalysts for the electrochemical incorporation of carbon dioxide into carbon-carbon double bonds. Different kind of olefin derivatives have been carboxylated to afford mono- or dicarboxylic acid derivatives depending on the alkene structure. The electrolyses are carried out in one compartment cells fitted with a magnesium anode under mild conditions.
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页码：5235 / 5248
页数：14
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