KINETIC RESOLUTION OF RACEMIC CARBOXYLIC-ACIDS AND ALCOHOLS WITH HOMOCHIRAL ALCOHOLS AND CARBOXYLIC-ACIDS, RESPECTIVELY, AND THE MUKAIYAMA OR PALOMO REAGENTS

被引：30
|
作者：
MAZON, A
NAJERA, C
YUS, M
HEUMANN, A
机构：
[1] UNIV ALICANTE,DEPT QUIM ORGAN,APDO 99,E-03080 ALICANTE,SPAIN
[2] UNIV AIX MARSEILLE,CTR ST JEROME,ENSSPICAM,URA 1410,F-13013 MARSEILLE,FRANCE
来源：
TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 11期
关键词：
D O I：
10.1016/0957-4166(92)80022-O
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Mukaiyama and Palomo reagents have been used for the kinetic resolution of racemic carboxylic acids or alcohols with homochiral alcohols or carboxylic acids, respectively, in the presence of triethylamine. Thus, enantiomerically enriched carboxylic acids (e.e.<68%), alcohols (e.e.<41%) or diastereoisomerically enriched esters (d.e.<84%) are obtained.
引用
收藏
页码：1455 / 1466
页数：12
相关论文
共 50 条
  • [41] SYNTHESIS OF AZIDES OF CARBOXYLIC-ACIDS
    SMUSHKEVICH, YI
    USOROV, MI
    ZHURNAL ORGANICHESKOI KHIMII, 1988, 24 (11): : 2450 - 2451
  • [42] TELOMERIZATION OF PROPYLENE WITH CARBOXYLIC-ACIDS
    CHURILOVA, MA
    POVOLOTSKII, DI
    TERENTEV, AB
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1975, 24 (11): : 2382 - 2386
  • [43] AZETIDINYL QUINOLONE CARBOXYLIC-ACIDS
    NAKANISHI, S
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 45 - MEDI
  • [44] CARBOXYLIC-ACIDS FROM SYNGAS
    KNIFTON, JF
    HYDROCARBON PROCESSING, 1981, 60 (12): : 113 - 117
  • [45] DICYANOPHOSPHINE INTERACTION WITH CARBOXYLIC-ACIDS
    PUDOVIK, AN
    NAZMUTDINOVA, VN
    CHIRKOVA, LP
    MUSIN, RZ
    ZHURNAL OBSHCHEI KHIMII, 1992, 62 (02): : 273 - 276
  • [46] AN EQUATION OF STATE FOR CARBOXYLIC-ACIDS
    TWU, CH
    COON, JE
    CUNNINGHAM, JR
    FLUID PHASE EQUILIBRIA, 1993, 82 : 379 - 388
  • [47] NITRODECARBOXYLATION OF PYRAZOLE CARBOXYLIC-ACIDS
    PEREVALOV, VP
    MANAEV, YA
    ANDREEVA, MA
    STEPANOV, BI
    ZHURNAL OBSHCHEI KHIMII, 1985, 55 (04): : 882 - 885
  • [48] REACTIONS OF OXAZAPHOSPHOLANES WITH CARBOXYLIC-ACIDS
    PUDOVIK, MA
    TERENTEVA, SA
    PUDOVIK, AN
    ZHURNAL OBSHCHEI KHIMII, 1981, 51 (03): : 518 - 526
  • [49] REACTION OF DIALKOXYPHOSPHORYLISOCYANATES WITH CARBOXYLIC-ACIDS
    NIKONOROV, KV
    LATYPOV, ZY
    ANTOKHINA, LA
    ZHURNAL OBSHCHEI KHIMII, 1982, 52 (11): : 2645 - 2646
  • [50] REACTION OF BENZYNE WITH CARBOXYLIC-ACIDS
    PAL, RS
    SHARMA, RP
    BOKADIA, MM
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1976, 53 (05) : 534 - 534
12345