DISTINCT REACTION PATHWAYS FOR SOME CLASSICAL AND NONCLASSICAL TRANSITION-METAL DIHYDRIDES

被引：14
|
作者：
BIANCHINI, C
PERUZZINI, M
ZANOBINI, F
机构：
[1] Istituto per lo Studio della Stereochimica ed Energetica dei Composti di Coordinazione, C. N. R., Via J. Nardi
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 390卷 / 01期
关键词：
D O I：
10.1016/0022-328X(90)85092-D
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chlorophosphine gold(I) compounds [Au(PR3)Cl] (R = Et, Ph) have been used as reagents for distinguishing classical from nonclassical structures in a family of dihydrides or dihydrogen complexes of iron, cobalt, rhodium and iridium stabilized by the tripodal polyphosphine PP3 [PP3 = P(CH2CH2PPh2)3]. Novel mixed transition-metal gold hydrides, including the first iron-gold species, are described. © 1990.
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页码：C16 / C19
页数：4
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