DISTINCT REACTION PATHWAYS FOR SOME CLASSICAL AND NONCLASSICAL TRANSITION-METAL DIHYDRIDES

被引:14
|
作者
BIANCHINI, C
PERUZZINI, M
ZANOBINI, F
机构
[1] Istituto per lo Studio della Stereochimica ed Energetica dei Composti di Coordinazione, C. N. R., Via J. Nardi
关键词
D O I
10.1016/0022-328X(90)85092-D
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Chlorophosphine gold(I) compounds [Au(PR3)Cl] (R = Et, Ph) have been used as reagents for distinguishing classical from nonclassical structures in a family of dihydrides or dihydrogen complexes of iron, cobalt, rhodium and iridium stabilized by the tripodal polyphosphine PP3 [PP3 = P(CH2CH2PPh2)3]. Novel mixed transition-metal gold hydrides, including the first iron-gold species, are described. © 1990.
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页码:C16 / C19
页数:4
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