ENHANCED SOLUBILIZATION OF AROMATIC SOLUTES IN AQUEOUS-SOLUTIONS OF N-VINYLPYRROLIDONE STYRENE

被引：21
|
作者：
HAULBROOK, WR [1 ]
FEERER, JL [1 ]
HATTON, TA [1 ]
TESTER, JW [1 ]
机构：
[1] MIT,ENERGY LAB,CAMBRIDGE,MA 02139
来源：
ENVIRONMENTAL SCIENCE & TECHNOLOGY | 1993年 / 27卷 / 13期
关键词：
D O I：
10.1021/es00049a017
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The partitioning behavior of several aromatic hydrocarbons between N-vinylpyrrolidone/styrene (NVPS) and water is reported. Values of log K(pw), concentration-based polymer-water partition coefficient, in this study are 3.39 +/- 0.04, 3.38 +/- 0.01, and 4.69 +/- 0.02 for toluene, naphthalene, and phenanthrene, respectively, in aqueous NVPS solution. A relationship between log K(pw) and log K(ow), octanol-water partition coefficient, is proposed to extend predictive analysis to other solutes. The high molecular weight (approximation 3.4 million g/mol) and high organic solubilization of NVPS make it attractive for use in organic-contaminated water remediation. Potential applications are briefly discussed.
引用
收藏
页码：2783 / 2788
页数：6
相关论文
共 50 条
  • [11] FRACTION OF N-VINYLPYRROLIDONE WITH SOLVENTS IN THE PRESENCE OF ACID IN AQUEOUS AND ALCOHOLIC SOLUTIONS
    DENISOV, VM
    USHAKOVA, VN
    KOLTSOV, AI
    PANARIN, EF
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1989, 62 (03): : 609 - 613
  • [12] EFFECT OF THE CHEMICAL-STRUCTURE OF POLY-N-VINYLAMIDES AND COPOLYMERS OF N-VINYLPYRROLIDONE ON THE STABILITY OF INTERPOLYMER COMPLEXES IN AQUEOUS-SOLUTIONS
    ANUFRIEVA, YV
    RAMAZANOVA, MR
    KRAKOVYAK, MG
    LUSHCHIK, VB
    NEKRASOVA, TN
    SHEVELEVA, TV
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1991, 33 (04): : 256 - 261
  • [13] ASSOCIATION BEHAVIOR OF PROTOPORPHYRIN IX IN WATER AND AQUEOUS POLY(N-VINYLPYRROLIDONE) SOLUTIONS - INTERACTION BETWEEN PROTOPORPHYRIN IX AND POLY(N-VINYLPYRROLIDONE)
    INAMURA, I
    UCHIDA, K
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (06) : 2005 - 2007
  • [14] Complexation of N-vinylpyrrolidone–N-allylamine copolymer with perrhenate ion in aqueous solutions
    N. I. Gorshkov
    Yu. V. Pokhvoshchev
    A. Yu. Murko
    O. V. Nazarova
    Yu. I. Zolotova
    V. D. Krasikov
    E. F. Panarin
    Doklady Chemistry, 2015, 462 : 137 - 140
  • [15] On the nature of macroradicals formed upon radiolysis of aqueous poly(N-vinylpyrrolidone) solutions
    Dispenza, Clelia
    Sabatino, Maria Antonietta
    Grimaldi, Natascia
    Dahlgren, Bjorn
    Al-Sheikhly, Mohamad
    Wishart, James F.
    Tsinas, Zois
    Poster, Dianne L.
    Jonsson, Mats
    RADIATION PHYSICS AND CHEMISTRY, 2020, 174 (174)
  • [16] Dynamic sorption of nitrophenols from aqueous solutions by polymers based on N-Vinylpyrrolidone
    Kushnir, A. A.
    Sukhanov, P. T.
    Churilina, E. V.
    Shatalov, G. V.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2014, 87 (05) : 579 - 584
  • [17] COMPLEXATION OF POLY(N-VINYLPYRROLIDONE) AND N-VINYLPYRROLIDONE COPOLYMERS WITH CUPRIC(II) IONS IN AQUEOUS-SOLUTION
    BEKTUROV, EA
    KUDAIBERGENOV, SE
    KANAPYANOVA, GS
    KURMANBAEVA, AA
    POLYMER COMMUNICATIONS, 1984, 25 (07): : 220 - 223
  • [18] Structure of poly-(N-vinylpyrrolidone) complexes with samarium diphthalocyanine in aqueous solutions
    Lebedev, VT
    Evmenenko, GA
    Alekseev, VL
    Orlova, DN
    Torok, G
    Cser, L
    Klyubin, VV
    Polyakov, AA
    Budtov, VP
    Moskalev, PN
    Sibileva, MA
    Sibilev, AI
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1999, 41 (07): : 1183 - 1190
  • [19] Dynamic sorption of nitrophenols from aqueous solutions by polymers based on N-Vinylpyrrolidone
    A. A. Kushnir
    P. T. Sukhanov
    E. V. Churilina
    G. V. Shatalov
    Russian Journal of Applied Chemistry, 2014, 87 : 579 - 584
  • [20] COPOLYMERIZATION OF BETA-PINENE WITH STYRENE OXIDE AND N-VINYLPYRROLIDONE
    MARTINEZ, F
    FLORSHEIM, R
    MARTINEZ, H
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1982, 20 (05) : 1279 - 1285
12345