PREPARATION AND CHARACTERIZATION OF ARYLTELLUROLATO-BRIDGED DINUCLEAR COMPLEXES OF PLATINUM(II)

被引：18

作者：

JAIN, VK ^{[1
]}

KANNAN, S ^{[1
]}

机构：

[1] BHABHA ATOM RES CTR,DIV FUEL CHEM,BOMBAY 400085,INDIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 418卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)80220-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of the type [Pt2Cl2(mu-X)(mu-TeAr)(PR3)2] (X = Cl or TeAr; Ar = Ph, 4-MeC6H4, 4-MeOC6H4, 4-EtOC6H4; PR3 = PEt3, PnBu3 or PMe2Ph) and [Pt2(mu-TeAr)2(P-C)2] (Ar = 4-MeC6H4, 4-MeOC6H4; P-C = tBu2PCMe2CH2) have been prepared. These complexes were characterized by elemental analyses, and multinuclear NMR (H-1, C-13, P-31, Te-125 and Pt-195) spectroscopy. The stereochemistry of the complexes in solution has been discussed on the basis of NMR data.

引用

页码：349 / 357

页数：9

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