MECHANISM OF THE FORMATION OF PRECURSORS FOR THE CU/ZNO METHANOL SYNTHESIS CATALYSTS BY A COPRECIPITATION METHOD

被引:52
|
作者
FUJITA, S
SATRIYO, AM
SHEN, GC
TAKEZAWA, N
机构
[1] Hokkaido University, Division of Materials Science and Engineering, Faculty of Engineering, Sapporo
关键词
PRECURSORS OF CU/ZNO CATALYSTS; COPRECIPITATION; PREPARATION OF AURICHALCITE;
D O I
10.1007/BF00808325
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Precursors of Cu/ZnO catalysts with various Cu/Zn molar ratios were prepared by a coprecipitation method. It was found that amorphous copper hydroxycarbonate and sodium zinc carbonate were intermediates for the formation of various precursors such as hydrozincite, malachite and aurichalcite. Aurichalcite having a high Cu/Zn ratio was prepared from a mechanical mixture of these intermediates.
引用
收藏
页码:85 / 92
页数:8
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