SCALING THEORY OF SUPERMOLECULAR STRUCTURES IN BLOCK COPOLYMER SOLVENT SYSTEMS .2. SUPERCRYSTALLINE STRUCTURES

被引：49
|
作者：
BIRSHTEIN, TM [1 ]
ZHULINA, EB [1 ]
机构：
[1] ACAD SCI USSR,INST MACROMOLEC COMPOUNDS,LENINGRAD,USSR
来源：
POLYMER | 1990年 / 31卷 / 07期
关键词：
composition-concentration diagram of state; concentrated solution of block copolymer; supermolecular structure;
D O I：
10.1016/0032-3861(90)90223-L
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The supermolecular structures formed in a block copolymer-solvent system were considered by using the scaling method. The equilibrium characteristics of the superstructures of different morphologies formed by two-block copolymers with non-crystallizable blocks were determined as a function of the molecular weight and composition of copolymer and the strength and concentration of the solvent in the system. The composition-concentration diagram of the system was obtained. The lamellar superstructure formed by a block copolymer with one crystallizable block was analysed. The results of the theory were compared with the experimental data. © 1990.
引用
收藏
页码：1312 / 1320
页数：9
相关论文
共 50 条
  • [31] FORMATION MECHANISM OF SUPERMOLECULAR STRUCTURES SiO2
    Kamashev, D.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2002, 58 : C160 - C160
  • [32] THEORY OF HELICOIDAL STRUCTURES IN ANTIFERROMAGNETS .2. METALS
    DZYALOSH.IE
    SOVIET PHYSICS JETP-USSR, 1965, 20 (01): : 223 - &
  • [33] ABSTRACT RELATIONAL STRUCTURES .2. (TORSION THEORY)
    FRIED, E
    WIEGANDT, R
    ALGEBRA UNIVERSALIS, 1982, 15 (01) : 22 - 39
  • [34] ARBORESCENT STRUCTURES .2. INTERPRETABILITY IN THE THEORY OF TREES
    SCHMERL, JH
    TRANSACTIONS OF THE AMERICAN MATHEMATICAL SOCIETY, 1981, 266 (02) : 629 - 643
  • [35] Controlled Formation of Silica Structures Using Siloxane/Block Copolymer Complexes Prepared in Various Solvent Mixtures
    Kataoka, Sho
    Takeuchi, Yasutaka
    Kawai, Akiko
    Yamada, Mitsuhiko
    Kamimura, Yoshihiro
    Endo, Akira
    LANGMUIR, 2013, 29 (44) : 13562 - 13567
  • [36] Block copolymer micellar cubic structures in ionic liquids
    Alexandridis, Paschalis
    Tsoutsoura, Aikaterini
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
  • [37] Mesoscopic Structures of Poly(carboxybetaine) Block Copolymer and Poly(ethylene glycol) Block Copolymer in Solutions
    Liao, Mingrui
    Liu, Hongyan
    Guo, Hongyu
    Zhou, Jian
    LANGMUIR, 2017, 33 (30) : 7575 - 7582
  • [38] Vesicular structures in mixed block copolymer/surfactant solutions
    Pispas, S.
    SOFT MATTER, 2011, 7 (19) : 8697 - 8701
  • [39] Crystallization in block copolymer melts: Small soft structures that template larger hard structures
    Fairclough, JPA
    Mai, SM
    Matsen, MW
    Bras, W
    Messe, L
    Turner, SC
    Gleeson, AJ
    Booth, C
    Hamley, IW
    Ryan, AJ
    JOURNAL OF CHEMICAL PHYSICS, 2001, 114 (12): : 5425 - 5431
  • [40] SCALING AND ROUNDOFF NOISE IN A CLASS OF MULTIRATE BLOCK STRUCTURES
    MIYAWAKI, T
    BARNES, CW
    IEEE TRANSACTIONS ON ACOUSTICS SPEECH AND SIGNAL PROCESSING, 1983, 31 (03): : 604 - 608
12345