THE ADSORPTION OF THIOSEMICARBAZIDE AT THE MERCURY PHOSPHORIC-ACID SOLUTION INTERFACE

被引：0

作者：

THIAGARAJAN, R ^{[1
]}

IYER, SV ^{[1
]}

机构：

[1] URMU DHANALAKSHMI COLL, Tiruchirappalli 620019, TAMIL NADU, INDIA

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1991年 / 30卷 / 11期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Adsorption of thiosemicarbazide on the mercury electrode from 0.2N phosphoric acid has been studied using a capillary electrometer. Electrocapillary curves have been obtained in the presence of different concentrations of the adsorbate. Thermodynamic parameters like charge on the metal surface (q(M)) and surface excess of organic molecules adsorbed (GAMMA-org) have been calculated. From the adsorPtion data, it is clearly seen that the adsorption of this compound obeys Temkin's adsorption isotherm. The variation of free energy of adsorption with charge on the metal surface has been explained.

引用

页码：959 / 963

页数：5

共 50 条

[41] ESTIMATION OF NITRATE IN PHOSPHORIC-ACID
KUTTY, TRN
CURRENT SCIENCE, 1973, 42 (01): : 18 - 19
[42] PHOSPHORIC-ACID ANALOGS OF PAF
HANAHAN, DJ
SUGIURA, T
GREGORY, L
NOUCHI, T
TOKUMURA, A
JOURNAL OF LIPID MEDIATORS AND CELL SIGNALLING, 1994, 10 (1-2): : 169 - 170
[43] ETHYLENE OLIGOMERIZATION ON PHOSPHORIC-ACID
VERESHCHAGIN, SN
SHISHKINA, NN
ANSHITS, AG
CATALYSIS TODAY, 1992, 13 (04) : 651 - 654
[44] DESTABILIZATION OF ZIRCONIA BY PHOSPHORIC-ACID
WILSON, HH
AMERICAN CERAMIC SOCIETY BULLETIN, 1978, 57 (04): : 455 - &
[45] NEPTUNIUM IONS IN PHOSPHORIC-ACID
COHEN, D
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1976, 172 (SEP3): : 28 - 28
[46] ON THE PHOSPHORIC-ACID IN POTATO STARCH
PALASINSKI, M
STARKE, 1980, 32 (12): : 405 - 408
[47] REACTION OF CAMPHOR WITH PHOSPHORIC-ACID
FUJITA, Y
FUJITA, S
YOSHIKAW.H
NIPPON KAGAKU ZASSHI, 1971, 92 (12): : 1220 - &
[48] GRANULATION WITH SLUDGE PHOSPHORIC-ACID
COOK, WH
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 198 : 38 - FERT
[49] PHOSPHINIC AND PHOSPHORIC-ACID HYDRAZIDES
SHANDRUK, MI
YANCHUK, NI
GREKOV, AP
ZHURNAL OBSHCHEI KHIMII, 1973, 43 (10): : 2194 - 2198
[50] SCRUBBERS FOR PHOSPHORIC-ACID PLANTS
HANSEN, AO
DANOS, RJ
CHEMICAL ENGINEERING PROGRESS, 1982, 78 (03) : 40 - 45

← 1 2 3 4 5 →