DEPROTECTION OF TETRAHYDROPYRANYL ETHERS WITH A MEXICAN BENTONITE SYNTHESIS OF FARNESYLHYDROQUINONE

被引:17
|
作者
CRUZALMANZA, R [1 ]
PEREZFLORES, FJ [1 ]
AVILA, M [1 ]
机构
[1] NATL AUTONOMOUS UNIV MEXICO,FAC ESTUDIOS SUPER CUAUTITLAN,SECC QUIM ORGAN,MEXICO CITY 04510,DF,MEXICO
关键词
D O I
10.1080/00397919008052819
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new method for deprotecting tetrahydropyranyl ethers has been established by using a bentonitic earth. The reaction proceeds selectively under mild conditions in good yields. The heterogenous reaction enables easy separation of the parent hydroxyl functionality by simple filtration. The synthesis of farnesylhydroquinone as a synthetic application of the method is also reported. Copyright © 1990 by Taylor & Francis Group. All rights reserved.
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页码:1125 / 1131
页数:7
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