SYNTHESIS OF THE TRIFLUOROACETATE SALT OF ASPARTIC-ACID BETA-SEMIALDEHYDE, AN INTERMEDIATE IN THE BIOSYNTHESIS OF L-LYSINE, L-THREONINE, AND L-METHIONINE

被引：0

作者：

TUDOR, DW

LEWIS, T

ROBINS, DJ

机构：

[1] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,SCOTLAND

[2] ICI AGROCHEM ZENECA LTD,JEALOTTS HILL RES STN,BRACKNELL RG12 6EY,BERKS,ENGLAND

来源：

SYNTHESIS-STUTTGART | 1993年 / 11期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The trifluoroacetate salt of aspartic acid beta-semialdehyde, an important intermediate in the biosynthesis Of L-lysine, L-threonine, and L-methionine has been prepared in DL-, L-, and D-forms as stable solid hydrates 13 in 43 % overall yield by ozonolysis of doubly protected allylglycine, followed by careful deprotection with trifluoroacetic acid.

引用

页码：1061 / 1062

页数：2

共 36 条

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[6] DIRECTED BIOSYNTHESIS OF PAULOMYCIN-A THE EFFECT OF L-METHIONINE, L-THREONINE AND ALPHA-KETOBUTYRIC ACID
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