RHEOLOGY OF ALUMINA SOLS

被引:7
|
作者
GONZALEZ, C
GUTIERREZ, J
LLORENS, J
GALAN, MI
MANS, C
机构
[1] Chemical Engineering Department, University of Barcelona, 08028 Barcelona
关键词
D O I
10.1016/S0022-3093(05)80700-8
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Alumina sols were obtained by hydrolysis of aluminium sec-butoxide according to Yoldas method. Peptization was carried out with two different quantities of HCl and at two different temperatures. The four sols obtained were stored at 40-degrees-C, and their rheological behaviour was determined for times to 1 year. Rheological measurements were fitted to a slightly modified Casson model. Evolution of adjusting parameters, yield stress, consistency index and flow index, with aging time, are discussed. Samples with higher HCl give a yield stress from the day of preparation. Samples with lower HCl display a Newtonian behaviour initially and shear thinning behaviour with increasing viscosity with aging time.
引用
收藏
页码:690 / 694
页数:5
相关论文
共 50 条
  • [41] Rheology of concentrated alumina-polyelectrolyte systems
    de Vasconcelos, CL
    Dantas, TNC
    Pereira, MR
    Fonseca, JLC
    COLLOID AND POLYMER SCIENCE, 2004, 282 (06) : 596 - 601
  • [42] Shear and compressive rheology of aggregated alumina suspensions
    Channell, GM
    Zukoski, CF
    AICHE JOURNAL, 1997, 43 (07) : 1700 - 1708
  • [43] Rheology, UV-vis transparency and particle size of modified Yoldas sols
    Dressler, M
    Nofz, M
    Gemeinert, M
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2006, 38 (03) : 261 - 269
  • [44] Rheology, UV-vis transparency and particle size of modified Yoldas sols
    M. Dressler
    M. Nofz
    M. Gemeinert
    Journal of Sol-Gel Science and Technology, 2006, 38 : 261 - 269
  • [45] Influence of polyvinylpyrrolidone (PVP) on alumina sols prepared by a modified Yoldas procedure
    Dressler, M.
    Nofz, M.
    Pauli, J.
    Jaeger, C.
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2008, 47 (03) : 260 - 267
  • [46] Microstructure evolution in chelated partially hydrolysed alumina sols during sonogelling
    Manoj M Hardias
    Jayesh R Bellare
    Bulletin of Materials Science, 1997, 20 (1) : 49 - 66
  • [47] Microstructure evolution in chelated partially hydrolysed alumina sols during sonogelling
    Haridas, MM
    Bellare, JR
    BULLETIN OF MATERIALS SCIENCE, 1997, 20 (01) : 49 - 66
  • [48] THERMALLY STABILIZED TRANSITIONAL ALUMINA PREPARED BY FUME PYROLYSIS OF BOEHMITE SOLS
    ISHIKAWA, T
    OHASHI, R
    NAKABAYASHI, H
    KAKUTA, N
    UENO, A
    FURUTA, A
    JOURNAL OF CATALYSIS, 1992, 134 (01) : 87 - 97
  • [49] Influence of polyvinylpyrrolidone (PVP) on alumina sols prepared by a modified Yoldas procedure
    M. Dressler
    M. Nofz
    J. Pauli
    C. Jäger
    Journal of Sol-Gel Science and Technology, 2008, 47 : 260 - 267
  • [50] Preparation of silica and alumina single oxides from commercial preformed sols
    Monaco, SJ
    Ko, EI
    CHEMISTRY OF MATERIALS, 1997, 9 (11) : 2404 - 2417