P-H-FUNCTIONALIZED YLIDE CARBENE COMPLEXES - SYNTHESIS OF [(CO)(5)M=C(OET)CH=P(NPR2I)(2)H] (M=CR, W) AND STRUCTURE OF THE CHROMIUM DERIVATIVE

被引：5

作者：

STREUBEL, R

HOBBOLD, M

JESKE, J

JONES, PG

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 21期

关键词：

D O I：

10.1039/c39940002457

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[(CO)(5)M=C(OEt)CH2Li] 1a,b (M: a, Cr; b, W) react with CIP(NPr2i)(2) 2 to yield the P-H-functionalized ylide-carbene complexes 4a,b via transiently formed [alpha-(phosphino)alkyl]carbene complexes 3a,b; compounds 4a,b are characterized by NMR spectroscopy (C-13, P-31) and complex 4a by single crystal X-ray diffraction.

引用

页码：2457 / 2458

页数：2

共 50 条

[41] Syntheses and Chemistry of the diynyl Complexes M(CCCCH)(CO)3(η-C5H5) (M = MO, W):: Crystal Structures of W(CCCCSiMe3)(CO)3 (η-C5H5), W{CCC[CH=C(CN)2]=C(CN)2}(CO)3(η-C5H5), and cis-W(CCPh)(CO)2(PPh3)(η-C5H5)
Bruce, MI
Ke, MZ
Low, PJ
Skelton, BW
White, AH
ORGANOMETALLICS, 1998, 17 (16) : 3539 - 3549
[42] SYNTHESIS, CRYSTAL-STRUCTURE, AND PROPERTIES OF DIPHENYLPHOSPHINITO-P-TRANSITION METAL(0) COMPLEXES OF THE TYPE [(C2H5)3NH][O(C6H5)2PM(CO)5] (M = CR, MO, W)
ZEIHER, C
HILLER, W
LORENZ, IP
CHEMISCHE BERICHTE-RECUEIL, 1985, 118 (08): : 3127 - 3134
[43] SYNTHESIS OF THE STERICALLY HINDERED COMPLEXES [M(CO)5(CNBR2)] [R=CH(SIME3)2, M=CR, MO, OR W] - CRYSTAL-STRUCTURE OF [CR(CO)5(CNBR2)]
BECK, G
LAPPERT, MF
HITCHCOCK, PB
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 468 (1-2) : 143 - 148
[44] REACTIVITY OF COORDINATED PH2P(C5H5) - PREPARATION OF M(CO)6-N[PH2P(C5H4TL)]N COMPLEXES (M = CR, MO, N = 1,2)
WONG, WK
LEE, FW
POLYHEDRON, 1992, 11 (08) : 863 - 870
[45] SYNTHESIS OF BINUCLEAR ORGANO-ALUMINUM COMPLEXES M[P-C5H11CH(ALR2)2X]
GAVRILENKO, VV
CHEKULAEVA, LA
ANTONOVICH, VA
ZAKHARKIN, LI
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1981, 30 (04): : 505 - 508
[46] NITROSYL COMPLEXES——SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURES OF （η5-C5H5）M（CO）2NO AND （η5-C5H5）M（μ3-NH）(μ2-NO)（μ2-CO）Fe2（CO）6（M=Mo OR W）
杨世琰
孙文华
殷元骐
郁开北
周忠远
Science China Chemistry, 1991, (11) : 1304 - 1311
[47] Theoretical investigation of the structure and nature of the interaction in metal-alkane σ-complexes of the type [M(CO)5(C2H6)] (M = Cr, Mo, and W)
Da Silva, Julio C. S.
De Almeida, Wagner B.
Rocha, Willian R.
CHEMICAL PHYSICS, 2009, 365 (1-2) : 85 - 93
[48] PHOTOCHEMICALLY-INDUCED DEGRADATION OF (ETA5-C5H5)M(CO)3CH3 COMPLEXES (M=CR,MO,W)
RAUSCH, MD
GISMONDI, TE
ALT, HG
SCHWARZLE, JA
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1977, 32 (09): : 998 - 1000
[49] CRYSTAL AND MOLECULAR STRUCTURE OF ISOMORPHOUS Cp2Cr2（CO）4（μ-η2-P2）[M（CO）5]2（M=Mo,W）
LAI YOONG GOH RICHARD C. S. WONGDepartment of Chemistry
结构化学, 1991, (02) : 89 - 92
[50] SYNTHESES AND MICHAEL ADDITIONS TO VINYLIDENE DIPHOSPHINE COMPLEXES OF TYPE [M(CO)4((PH2P)2C=CH2)] (M = CR, MO OR W)
COOPER, GR
MCEWAN, DM
SHAW, BL
INORGANICA CHIMICA ACTA, 1986, 122 (02) : 207 - 211

← 1 2 3 4 5 →