STRUCTURE AND REACTIVITY OF [HFE(CO)3-ETA(3)-C3H5)]

被引:0
|
作者
BARNHART, TM [1 ]
DEFELIPPIS, J [1 ]
MCMAHON, RJ [1 ]
机构
[1] UNIV WISCONSIN, DEPT CHEM, MADISON, WI 53706 USA
关键词
D O I
10.1002/anie.199310731
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Postulated 30 years ago, the highly reactive intermediate 1 of the Fe(CO)5-catalyzed alkene isomerization was observed for the first time in solution by NMR spectroscopy. The ability to generate and monitor such reactive species opens the way for detailed investigations of this important reaction.
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页码:1073 / 1074
页数:2
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