THE FREE-RADICAL POLYMERIZATION OF ACRYLAMIDE INITIATED WITH CERIC SULFATE IN THE PRESENCE OF AMINO-ACIDS

被引：22

作者：

ERBIL, C ^{[1
]}

SOYDAN, AB ^{[1
]}

AROGUZ, AZ ^{[1
]}

SARAC, AS ^{[1
]}

机构：

[1] ISTANBUL UNIV,DEPT CHEM,ISTANBUL,TURKEY

来源：

ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1993年 / 213卷

关键词：

D O I：

10.1002/apmc.1993.052130107

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymerization of acrylamide initiated with ceric(IV) ion in the presence of methionine, phenylalanine, serine and aspartic acid was investigated in sulfuric acid solution. Maximum yield was obtained at 70-degrees-C and sulfuric acid concentration of 0.16 mol/l. Both conductometric titration and FT-IR results showed that the resulting polymers contained carboxy end groups. According to these findings and previous studies in this field, a suitable polymerization mechanism was proposed.

引用

页码：55 / 63

页数：9

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