THE FREE-RADICAL POLYMERIZATION OF ACRYLAMIDE INITIATED WITH CERIC SULFATE IN THE PRESENCE OF AMINO-ACIDS

被引：22
|
作者：
ERBIL, C [1 ]
SOYDAN, AB [1 ]
AROGUZ, AZ [1 ]
SARAC, AS [1 ]
机构：
[1] ISTANBUL UNIV,DEPT CHEM,ISTANBUL,TURKEY
来源：
ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1993年 / 213卷
关键词：
D O I：
10.1002/apmc.1993.052130107
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Polymerization of acrylamide initiated with ceric(IV) ion in the presence of methionine, phenylalanine, serine and aspartic acid was investigated in sulfuric acid solution. Maximum yield was obtained at 70-degrees-C and sulfuric acid concentration of 0.16 mol/l. Both conductometric titration and FT-IR results showed that the resulting polymers contained carboxy end groups. According to these findings and previous studies in this field, a suitable polymerization mechanism was proposed.
引用
收藏
页码：55 / 63
页数：9
相关论文
共 50 条
  • [1] FREE-RADICAL POLYMERIZATION OF ACRYLAMIDE
    SILVERSMITH, EF
    WOLSEY, WC
    JOURNAL OF CHEMICAL EDUCATION, 1992, 69 (09) : 763 - 763
  • [2] POLYMERIZATION OF ACRYLAMIDE INITIATED WITH CERIC ION IN PRESENCE OF FERRIC ION
    NARITA, H
    OKAMOTO, S
    MACHIDA, S
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1968, 111 (FEB): : 14 - &
  • [3] FREE-RADICAL INITIATED POLYMERIZATION
    PERCEC, V
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 188 (AUG): : 3 - POLY
  • [4] POLYMERIZATION OF ACRYLAMIDE INITIATED WITH CERIC ION
    NARITA, H
    MACHIDA, S
    MAKROMOLEKULARE CHEMIE, 1966, 97 (SEP): : 209 - &
  • [5] FREE-RADICAL INITIATED POLYMERIZATION OF DIETHYLFUMARATE
    BENGOUGH, WI
    PARK, GB
    YOUNG, RA
    EUROPEAN POLYMER JOURNAL, 1975, 11 (04) : 305 - 308
  • [6] UV-Initiated free-radical polymerization of acrylamide based glucose and galactose glycomonomers
    Lewis, Sally
    Fogel, April
    Morgan, Sarah
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [7] Free-radical trapping in the precipitation polymerization of acrylamide
    Guha, S
    Rao, TRG
    Mandal, BM
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2003, 41 (11) : 1192 - 1197
  • [8] PHOTOSENSITIVITY OF CERIC ION INITIATED ACRYLAMIDE POLYMERIZATION
    董建华
    丘坤元
    冯新德
    Chinese Journal of Polymer Science, 1992, (02) : 164 - 168
  • [9] FREE-RADICAL INITIATED POLYMERIZATION OF VINYL MONOMERS
    BUTLER, GB
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1982, 184 (SEP): : 27 - POLY
  • [10] FREE-RADICAL POLYMERIZATION IN PRESENCE OF TRIETHYLBORANE
    ABUIN, E
    CORNEJO, J
    LISSI, EA
    EUROPEAN POLYMER JOURNAL, 1975, 11 (11) : 779 - 782
12345