A convenient synthesis of new sugar amino acid: 3-aminomethyl-3-deoxy-1,2-O-isopropylide-alpha-D-ribo-hexofuranuronic acid

被引：0
|
作者：
Turks, M [1 ]
Katkevica, D [1 ]
Smits, H [1 ]
Bizdena, E [1 ]
机构：
[1] Riga Tech Univ, Fac Chem Technol, LV-1048 Riga, Latvia
来源：
CHEMISTRY OF NUCLEIC ACID COMPONENTS | 1999年 / 2卷
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D O I：
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中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Efficient synthesis of protected 3-aminomethyl-3-deoxy-1,2-O-isopropylidene-alpha-D-ribo-hexofuranuronic acid 1 has been developed. The key reaction in this route is the creation of new C-C bonds in positions C(3) and C(5), which was achieved by nitromethane addition to carbonyl derivatives of sugar (Henry reaction).
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页码：268 / 272
页数：5
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