STEROID ALKALOID GLYCOSIDES FROM SOLANUM-ROBUSTUM

被引:0
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作者
RIPPERGER, H
PORZEL, A
机构
来源
关键词
SOLANUM-ROBUSTUM; BETA(1)-SOLAMARGINE; ROBUSTINE; SOLASODINE DERIVATIVES; STEROIDS; ALKALOIDS; GLYCOSIDES; CARBOHYDRATES;
D O I
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Beta1-Solamargine and three new glycoalkaloids, robustine, N-hydroxyrobustine, and 25-acetoxyrobustine, have been isolated from the roots of Solanum robustum, the structures of which have been elucidated as 3-O-{O-alpha-L-arabinopyrano-syl-(1-->3)-O-[alpha-L-rhamnopyranosyl-(1-->2)]-O-[alpha-L-rhamno-pyranosyl-(1-->4)]-beta-D-glucopyranosyl}solasodine (3), its N-hydroxy, and its 25-acetoxy derivative. These compounds have characteristic structures in comparison with the hitherto known Solanum glycoalkaloids.
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页码:517 / 520
页数:4
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