A CALCULATION OF RADIATIVE LIFETIMES OF ELECTRONICALLY EXCITED ROVIBRONIC LEVELS OF CUF

被引：14
|
作者：
SCHAMPS, J
DELAVAL, JM
FAUCHER, O
机构：
[1] Laboratoire de Spectroscopie Moléculaire, Unité de Recherche Associée au CNRS No. 779, Molécules Diatomiques, Université des Sciences et Techniques de Lille Flandres Artois, UFR de Physique, Bâtiment P5
来源：
CHEMICAL PHYSICS | 1990年 / 145卷 / 01期
关键词：
D O I：
10.1016/0301-0104(90)80121-D
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Radiative lifetimes for rovibronic levels of the excited valence states of CuF are calculated using a model including both spin-orbit and Coriolis interactions. According to a discussion concerning their decay mechanisms, the spin-orbit components are classified into three classes with lifetimes differing by several orders of magnitude. Electronic transition intensity patterns are calculated and compared with spectroscopic observations. © 1990.
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页码：101 / 110
页数：10
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