ROTATIONALLY RESOLVED PHOTOELECTRON-SPECTROSCOPY OF THE [A(1)DELTA]3D-PI(2)PHI RYDBERG STATE OF THE SH RADICAL

被引：11

作者：

MILAN, JB ^{[1
]}

BUMA, WJ ^{[1
]}

DELANGE, CA ^{[1
]}

WANG, KH ^{[1
]}

MCKOY, V ^{[1
]}

机构：

[1] CALTECH,ARTHUR AMOS NOYES LAB CHEM PHYS,PASADENA,CA 91125

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 103卷 / 08期

关键词：

D O I：

10.1063/1.470258

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Results of calculated and measured photoelectron spectra via the [a (1) Delta]3d pi (2) Phi state of SH are reported. These spectra show a strong asymmetry away from classical expectations and only transitions up to Delta N=+/-2 are observed, in contrast to Delta N=+/-4 expected for photoionization of a 3d pi orbital. Agreement between the calculated and measured spectra is excellent. (C) 1995 American Institute of Physics.

引用

页码：3262 / 3264

页数：3

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