ROTATIONALLY RESOLVED PHOTOELECTRON-SPECTROSCOPY OF THE [A(1)DELTA]3D-PI(2)PHI RYDBERG STATE OF THE SH RADICAL

被引：11
|
作者：
MILAN, JB [1 ]
BUMA, WJ [1 ]
DELANGE, CA [1 ]
WANG, KH [1 ]
MCKOY, V [1 ]
机构：
[1] CALTECH,ARTHUR AMOS NOYES LAB CHEM PHYS,PASADENA,CA 91125
来源：
JOURNAL OF CHEMICAL PHYSICS | 1995年 / 103卷 / 08期
关键词：
D O I：
10.1063/1.470258
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Results of calculated and measured photoelectron spectra via the [a (1) Delta]3d pi (2) Phi state of SH are reported. These spectra show a strong asymmetry away from classical expectations and only transitions up to Delta N=+/-2 are observed, in contrast to Delta N=+/-4 expected for photoionization of a 3d pi orbital. Agreement between the calculated and measured spectra is excellent. (C) 1995 American Institute of Physics.
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页码：3262 / 3264
页数：3
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