EFFECT OF ADDITION OF PD, CO AND PD-CO ON CEO2 - SYNGAS CONVERSION AND ACETALDEHYDE REACTION

被引：0
|
作者：
IDRISS, H [1 ]
DIAGNE, C [1 ]
HINDERMANN, JP [1 ]
KINNEMANN, A [1 ]
BARTEAU, MA [1 ]
机构：
[1] UNIV DELAWARE, DEPT CHEM ENGN, NEWARK, DE 19716 USA
来源：
STUDIES IN SURFACE SCIENCE AND CATALYSIS | 1993年 / 75卷
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ethanol was observed from the reaction of CO/H-2+ CH2Cl2 on Pd/CeO2 as well as from the reaction of CO/H-2 On Pd-CO/CeO2. This result clearly indicates that Co sites provide CH(x) species responsible for ethanol formation. Intimate contact between Pd and Co was most likely formed since TPR indicated that both metals were reduced at the same temperature. Moreover, acetaldehyde TPD showed that ethanol produced by acetaldehyde hydrogenation desorbed at only one peak temperature which might be indicative of a single type of active site.
引用
收藏
页码：2119 / 2122
页数：4
相关论文
共 50 条
  • [41] Effects of precipitants and surfactants on catalytic activity of Pd/CeO2 for CO oxidation
    Yue Zhou
    Xin Liu
    Qiulin Zhang
    Qixian Liu
    Zhongxian Song
    Ping Ning
    Research on Chemical Intermediates, 2017, 43 : 6187 - 6205
  • [42] Effect of CeO2 on CO removal over CeO2-modified Ni catalyst in CO-rich syngas
    Sung Ho Kim
    Weon-Doo Lee
    Ho-In Lee
    Korean Journal of Chemical Engineering, 2013, 30 : 860 - 863
  • [43] Effect of CeO2 on CO removal over CeO2-modffied Ni catalyst in CO-rich syngas
    Kim, Sung Ho
    Lee, Weon-Doo
    Lee, Ho-In
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2013, 30 (04) : 860 - 863
  • [44] FERROMAGNETIC TRANSITION IN DILUTE PD-CO ALLOYS
    PILIPOWICZ, A
    CLAUS, H
    PHYSICAL REVIEW B, 1987, 36 (01): : 773 - 775
  • [45] MAGNETIC TRANSITION IN HYDROGENATED PD-CO ALLOYS
    SOUFFACHE, B
    BURGER, JP
    JOURNAL DE PHYSIQUE, 1982, 43 (11): : 1717 - 1720
  • [46] Effect of Pd doping in (Fe/Ni)/CeO2 catalyst for the reaction path in CO2 oxidative ethane dehydrogenation/reforming
    Li, Xiuquan
    Yang, Zhongqing
    Zhang, Li
    He, Ziqiang
    Fang, Ruiming
    Wang, Ziqi
    Yan, Yunfei
    Ran, Jingyu
    ENERGY, 2021, 234
  • [47] CeO2 supported Pd dimers boosting CO2 hydrogenation to ethanol
    Lou, Yang
    Jiang, Feng
    Zhu, Wen
    Wang, Li
    Yao, Tingyi
    Wang, Shanshan
    Yang, Bo
    Yang, Bing
    Zhu, Yongfa
    Liu, Xiaohao
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2021, 291
  • [48] KONDO BEHAVIOR IN HYDROGENATED PD-CO ALLOYS
    SENOUSSI, S
    BURGER, JP
    SOUFFACHE, B
    PHYSICS LETTERS A, 1975, 54 (04) : 288 - 290
  • [49] Effect of Re addition on the activities of Co/CeO2 catalysts for water gas shift reaction
    Chayakul, Kingkaew
    Srithanratana, Tipaporn
    Hengrasmee, Sunantha
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2011, 340 (1-2) : 39 - 47
  • [50] Oxygen Vacancy in CeO2 Facilitate the Catalytic Activity of Pd/CeO2 for CO Direct Esterification to Dimethyl Oxalate
    Chao Hu
    Kai-Qiang Jing
    Xiao-Qi Lin
    Jing Sun
    Zhong-Ning Xu
    Guo-Cong Guo
    Catalysis Letters, 2022, 152 : 503 - 512
12345