ION DIPOLE MODEL PERTURBATION-THEORY APPLIED TO SIMPLE ELECTROLYTES

被引：17
|
作者：
CHAN, KY
机构：
[1] Department of Chemistry, University of Hong Kong, HKG
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 19期
关键词：
D O I：
10.1021/j100172a064
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An application of the ion-dipole perturbation theory developed by Henderson, Blum, and Tani is attempted. Expressions for the activity coefficient and methods of predicting density changes are reported. These are tested against experimental data of chloride solutions. The serious disagreement shown is mainly due to failure in predicting the reference hard-sphere fluid properties.
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页码：7465 / 7471
页数：7
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