ACTIVATED RATE-PROCESSES - A MULTIDIMENSIONAL KRAMERS TURNOVER THEORY

被引:20
|
作者
POLLAK, E
HERSHKOWITZ, E
机构
[1] Chemical Physics Department, Weizmann Institute of Science, Rehovot
关键词
D O I
10.1016/0301-0104(93)E0425-U
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The turnover theory for activated rate processes is generalized to include multidimensional strongly coupled systems. A uniform expression for the rate, valid for all damping values is derived and applied to numerical simulation results of Straub and Berne. The theory is applicable to both space and time dependent friction.
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页码:191 / 197
页数:7
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