HIGHLY TWISTED SUBSTITUTED ARENES - X-RAY STRUCTURE AND DYNAMIC H-1-NMR SPECTRA OF 1,4-DIALKYL-2,3,5,6-TETRAKIS(ALKYLSULFONYL)BENZENES

被引:6
|
作者
COLLARD, DM [1 ]
SADRI, MJ [1 ]
VANDERVEER, D [1 ]
HAGEN, KS [1 ]
机构
[1] EMORY UNIV,DEPT CHEM,ATLANTA,GA 30322
关键词
D O I
10.1039/c39950001357
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The sulfonyl groups around 1,4-disubstituted-2,3,5,6-tetrakis(alkylsulfonyl)benzenes adopt an altering orientation and the ring is highly twisted, with external torsion angles (S-C-ar-C-ar-S) of 46 degrees and internal torsion angles(C-ar-C-ar-CarCar) of 23 degrees.
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页码:1357 / 1358
页数:2
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