NEUTRAL ALKYLATION OF CHIRAL ALLYLIC CYCLIC CARBONATES CATALYZED BY PALLADIUM COMPLEX

被引：24
|
作者：
KANG, SK
KIM, SG
LEE, JS
机构：
[1] Department of Chemistry, Sung Kyun Kwan University, Suwon, 440-746, Natural Science Campus
来源：
TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 09期
关键词：
D O I：
10.1016/S0957-4166(00)82096-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The cyclic carbonates of acyclic vinyl diols react with nucleophiles in the presence of a palladium complex as a catalyst under neutral conditions to afford alkylated (E)-allylic alcohols with highly regio-, and diastereoselectivity. This reaction represents an efficient 1,3-chirality transfer method.
引用
收藏
页码：1139 / 1140
页数：2
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