FINGERPRINT IDENTIFICATION OF ORGANIC-COMPOUNDS USING AN OSCILLATING PLASMA GLOW-DISCHARGE DETECTOR FOR GAS-CHROMATOGRAPHY

被引：14

作者：

SMITH, DL ^{[1
]}

PIEPMEIER, EH ^{[1
]}

机构：

[1] OREGON STATE UNIV,DEPT CHEM,CORVALLIS,OR 97331

来源：

ANALYTICAL CHEMISTRY | 1994年 / 66卷 / 08期

关键词：

D O I：

10.1021/ac00080a018

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

An oscillating plasma glow discharge detector for gas chromatography can be used to help identify an analyte by combining the current and oscillation frequency signals. Five homologs each of the n-alkanes, 1-alkenes, 1-alkynes, 2-ketones, and aldehydes were studied. Although triplicate determinations had some scatter due to noise, they showed clustering that allows several of these compounds to be distinguished from the others by using a two-dimensional plot of the ratios of frequency peak area to current peak area and frequency peak height to current peak height.

引用

页码：1323 / 1329

页数：7

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