DIMERIZATION OF AROMATIC-ALDEHYDES CATALYZED BY K[CPFE(CO)(2)]

被引：7

作者：

OHISHI, T ^{[1
]}

SHIOTANI, Y ^{[1
]}

YAMASHITA, M ^{[1
]}

机构：

[1] DOSHISHA UNIV,FAC ENGN,DEPT MOLEC SCI & TECHNOL,TANABE,KYOTO 61003,JAPAN

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 11期

关键词：

D O I：

10.1021/om00023a076

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

K[CpFe(CO)(2)] was found to be an efficient catalyst for the dimerization of aromatic aldehydes to carboxylic esters. In the reactions of para-substituted aromatic aldehydes, the reactivity increased with a decrease in the electron density of their carbonyl carbon. On the basis of these results, the reaction mechanism including the nucleophilic attack of [CpFe(CO)(2)](-) (Fp anion) at the carbonyl carbon is discussed.

引用

页码：4641 / 4642

页数：2

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