EXPERIMENTAL-STUDY OF ELEMENTARY REACTIONS OF FO RADICALS .1. SOURCES AND MEASUREMENT OF ABSOLUTE CONCENTRATIONS - THE REACTION F+O3[-FO+O-2

被引：0
|
作者：
BEDZHANYAN, YR
MARKIN, EM
GERSHENZON, YM
机构：
来源：
KINETICS AND CATALYSIS | 1992年 / 33卷 / 04期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An experimental setup for studying elementary reactions of FO radicals was described. Methods of generating FO radicals and the procedure for measuring their absolute concentrations were examined. The reaction: F + O3 --> FO + O2 was investigated in jet conditions with an ESR/IR LMR spectrometer. The value of k = (6.2 +/- 0.3).10(-12) cm3.sec-1 was obtained for the reaction rate constant at room temperature.
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页码：594 / 601
页数：8
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