EXPERIMENTAL-STUDY OF ELEMENTARY REACTIONS OF FO RADICALS .1. SOURCES AND MEASUREMENT OF ABSOLUTE CONCENTRATIONS - THE REACTION F+O3[-FO+O-2

被引：0

作者：

BEDZHANYAN, YR

MARKIN, EM

GERSHENZON, YM

机构：

来源：

KINETICS AND CATALYSIS | 1992年 / 33卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An experimental setup for studying elementary reactions of FO radicals was described. Methods of generating FO radicals and the procedure for measuring their absolute concentrations were examined. The reaction: F + O3 --> FO + O2 was investigated in jet conditions with an ESR/IR LMR spectrometer. The value of k = (6.2 +/- 0.3).10(-12) cm3.sec-1 was obtained for the reaction rate constant at room temperature.

引用

页码：594 / 601

页数：8

共 50 条

[1] EXPERIMENTAL-STUDY OF ELEMENTARY REACTIONS OF FO RADICALS .6. REACTION WITH NO2
BEDZHANYAN, YR
MARKIN, EM
GERSHENZON, YM
KINETICS AND CATALYSIS, 1993, 34 (02) : 190 - 193
[2] EXPERIMENTAL-STUDY OF ELEMENTARY REACTIONS OF FO RADICALS .2. KINETICS AND MECHANISM OF THE DISPROPORTIONATION REACTION
BEDZHANYAN, YR
MARKIN, EM
GERSHENZON, YM
KINETICS AND CATALYSIS, 1992, 33 (04) : 601 - 606
[3] EXPERIMENTAL-STUDY OF ELEMENTARY REACTIONS OF FO RADICALS .3. REACTIONS WITH OXYGEN AND NITROGEN-ATOMS
BEDZHANYAN, YR
MARKIN, EM
POLITENKOVA, GG
GERSHENZON, YM
KINETICS AND CATALYSIS, 1992, 33 (5-6) : 797 - 801
[4] EXPERIMENTAL-STUDY OF ELEMENTARY REACTIONS OF FO RADICALS .5. REACTIONS WITH H-2, CO AND NO
BEDZHANYAN, YR
MARKIN, EM
GERSHENZON, YM
KINETICS AND CATALYSIS, 1993, 34 (01) : 1 - 4
[5] EXPERIMENTAL-STUDY OF ELEMENTARY REACTIONS OF FO RADICALS .4. REACTIONS WITH HYDROGEN-ATOMS
BEDZHANYAN, YR
MARKIN, EM
GERSHENZON, YM
KINETICS AND CATALYSIS, 1992, 33 (5-6) : 802 - 807
[6] An ab initio study on the mechanism of the F+O3 → FO+O2 reaction:: comparative reactivity study along the isoelectronic NH2, OH and F radicals series
Peiró-García, J
Nebot-Gil, I
CHEMICAL PHYSICS LETTERS, 2004, 391 (1-3) : 195 - 199
[7] Experimental study of elementary reactions of FO2• radicals:: I.: Generation, registration, and concentration measurements
Bedzhanyan, YR
Gershenzon, YM
Il'in, SD
KINETICS AND CATALYSIS, 1999, 40 (04) : 443 - 451
[8] AN AB-INITIO STUDY OF THE REACTION BETWEEN FO RADICALS AND H2O
FRANCISCO, JS
SU, Y
CHEMICAL PHYSICS LETTERS, 1993, 215 (1-3) : 58 - 62
[9] KINETICS OF THE REACTION OF F-ATOMS WITH O2 AND UV SPECTRUM OF FO2 RADICALS IN THE GAS-PHASE AT 295-K
ELLERMANN, T
SEHESTED, J
NIELSEN, OJ
PAGSBERG, P
WALLINGTON, TJ
CHEMICAL PHYSICS LETTERS, 1994, 218 (04) : 287 - 294
[10] ATMOSPHERIC CHEMISTRY OF FO2 RADICALS - REACTION WITH CH4, O-3, NO, NO2, AND CO AT 295-K
SEHESTED, J
SEHESTED, K
NIELSEN, OJ
WALLINGTON, TJ
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (27): : 6731 - 6739

← 1 2 3 4 5 →