trans-Bis(acetato-kappa O)bis(2-amino-ethanol-kappa N-2, O) nickel(II)

被引：4

作者：

Bazarjani, Mandi Seifollahi ^{[1
]}

Foro, Sabine ^{[1
]}

Donner, Wolfgang ^{[1
]}

Gurlo, Aleksander ^{[1
]}

Riedel, Ralf ^{[1
]}

机构：

[1] Tech Univ Darmstadt, Fachbereich Mat & Geowissensch, Petersenstr 23, D-64287 Darmstadt, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

D O I：

10.1107/S1600536812014237

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Ni(CH3CO2)(2)(C2H7NO)(2)], the Ni II cation, located on an inversion center, is N, O-chelated by two 2-aminoethanol molecules and further coordinated by two monodendate acetate anions in a slightly distorted octahedral geometry. The latter is stabilized by intramolecular O-H center dot center dot center dot O hydrogen bonds involving the non-coordinated O atom of the acetate and the H atom of the hydroxy group of the 2-aminoethanol ligand. In the crystal, N-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional supramolecular framework that involves (a) the coordinated acetate O atom and one of the H atoms of the amino group and (b) the non-coordinated acetate O atom and the other H atom of the amino group.

引用

页码：M567 / +

页数：9

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