DINITRAMIDE AND ITS SALTS .1. SYNTHESIS OF DINITRAMIDE SALTS BY DECYANOETHYLATION OF N,N-DINITRO-BETA-AMINOPROPIONITRILE

被引:59
|
作者
LUKYANOV, OA
GORELIK, VP
TATAKOVSKII, VA
机构
[1] N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 117913
关键词
DINITRAMIDE; DINITRAMIDE SALTS; NITROSULFAMIDES; DECYANOETHYLATION; MICHAEL REACTION; METHYLATION;
D O I
10.1007/BF00699142
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A strategy of organic synthesis has been developed for a new class of inorganic compounds, viz., dinitramide and its metal, ammonium, and substituted ammonium salts. The basic concepts have been tested in model reactions of beta-substituted derivatives of N-alkyl-N-nitrotoluenesulfonamides with bases and hate been confirmed by the decyanoethyiation of N,N-dinitro-beta-aminopropionitrile taken as an example.
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页码:89 / 92
页数:4
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