OXIDATIVE CONVERSION OF METHANE OVER MGO/ZSM-5 CATALYSTS

被引：0
|
作者：
KOVACHEVA, P [1 ]
DAVIDOVA, N [1 ]
WEISS, AH [1 ]
机构：
[1] WORCESTER POLYTECH INST,DEPT CHEM ENGN,WORCESTER,MA 01609
来源：
NEW DEVELOPMENTS IN SELECTIVE OXIDATION II | 1994年 / 82卷
关键词：
D O I：
暂无
中图分类号：
F [经济];
学科分类号：
02 ;
摘要：
Increased selectivity to C-2 hydrocarbons in the oxidative conversion of methane is obtained as a result of the addition of 1-10 wt.% MgO to ZSM-5. Sodium promotion of MgO/ZSM-5 improves the C-2 Selectivity to 100%, but leads to lower stability of the catalyst in the reaction conditions examined. It is established, that the availability of zeolitic basic sites is of great significance for the interpretation of the catalytic activity and selectivity of MgO/ZSM-5 catalysts.
引用
收藏
页码：403 / 409
页数：7
相关论文
共 50 条
  • [31] XAFS characterization of Mo/ZSM-5 catalysts for methane conversion to benzene: Effect of additives
    Kubota, Takeshi
    Oshima, Nobuyuki
    Nakahara, Yasuyuki
    Yanagimoto, Maki
    Okamoto, Yasuaki
    JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 2006, 49 (03) : 127 - 133
  • [32] Nonoxidative conversion of methane into aromatic hydrocarbons on Ni-Mo/ZSM-5 catalysts
    A. V. Vosmerikov
    V. I. Zaikovskii
    L. L. Korobitsyna
    G. V. Echevskii
    V. V. Kozlov
    Ya. E. Barbashin
    S. P. Zhuravkov
    Kinetics and Catalysis, 2009, 50 : 725 - 733
  • [33] XPS and FTIR studies of Mo/ZSM-5 catalysts for nonoxidative conversion of methane to aromatics
    Chen, HY
    Tang, S
    Zhong, ZY
    Lin, J
    Tan, KL
    SURFACE REVIEW AND LETTERS, 2001, 8 (06) : 627 - 632
  • [34] Nonoxidative Conversion of Methane into Aromatic Hydrocarbons on Ni-Mo/ZSM-5 Catalysts
    Vosmerikov, A. V.
    Zaikovskii, V. I.
    Korobitsyna, L. L.
    Echevskii, G. V.
    Kozlov, V. V.
    Barbashin, Ya. E.
    Zhuravkov, S. P.
    KINETICS AND CATALYSIS, 2009, 50 (05) : 725 - 733
  • [35] Effects of added phosphorus on conversion of ethanol to propylene over ZSM-5 catalysts
    Takahashi, Atsushi
    Xia, Wei
    Nakamura, Isao
    Shimada, Hiromichi
    Fujitani, Tadahiro
    APPLIED CATALYSIS A-GENERAL, 2012, 423 : 162 - 167
  • [36] Conversion of methane to benzene over Mo2C and Mo2C/ZSM-5 catalysts
    Solymosi, F.
    Szoeke, A.
    Cserenyi, J.
    Catalysis Letters, 39 (3-4):
  • [37] THE CONVERSION OF ETHANOL TO HYDROCARBONS OVER ZSM-5
    SAHA, SK
    SIVASANKER, S
    INDIAN JOURNAL OF TECHNOLOGY, 1992, 30 (02): : 71 - 76
  • [38] Optimization of methane conversion to liquid fuels over W-Cu/ZSM-5 catalysts by response surface methodology
    Anggoro, Didi Dwi
    Istadi
    JOURNAL OF NATURAL GAS CHEMISTRY, 2008, 17 (01): : 39 - 44
  • [39] Optimization of methane conversion to liquid fuels over W-Cu/ZSM-5 catalysts by response surface methodology
    Didi Dwi Anggoro
    Istadi
    Journal of Natural Gas Chemistry, 2008, (01) : 39 - 44
  • [40] Conversion of methane to benzene over Mo2C and Mo2C/ZSM-5 catalysts
    Solymosi, F
    Szoke, A
    Cserenyi, J
    CATALYSIS LETTERS, 1996, 39 (3-4) : 157 - 161
12345