PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .24. EQUILIBRIUM IN SOLUTIONS OF METAL(II) COMPLEXES WITH METHACROYLACETONE

被引：3
|
作者：
MOVCHAN, TI
ZHELTVAI, II
VOLOSHANOVSKII, IS
POMOGAILO, AD
机构：
[1] II MECHNIKOV ODESSA STATE UNIV,ODESSA 270000,UKRAINE
[2] ODESSA PHYS CHEM INST,ODESSA 270050,UKRAINE
来源：
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE | 1992年 / 41卷 / 09期
关键词：
ALKALINE-EARTH METALS; 3D METALS; METHACROYLACETONE; IONIC STRENGTH; PH-METER METHOD; TRANSITION-METAL COMPLEXES;
D O I：
10.1007/BF00863581
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Stability constants of Mg, Ca, Sr, Ba Mn, Co, Ni, Cu, and Zn complexes with the polymerizable ligand methacrylacetone have been determined in aqueous-dioxane solutions at an ionic strength of mu = 0.1 at 22-degrees-C. The methacroylacetone was shown to contain approximately 30% in the enol form using the pH-meter method. The stability sequence of the transition-metal complexes corresponds to the Irving - Williams stability series for ligands of low molecular weight; for the alkaline-earth metals the stability of the complexes increases with increase in ionic radius. Methacroylacetone-based chelates are significantly less stable than their analogs with unsubstituted acetylacetone.
引用
收藏
页码：1609 / 1614
页数：6
相关论文
共 50 条
  • [21] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .32. SPECTROSCOPIC STUDY OF THE POLYMERIZATION PRODUCT OF CU(II) ACRYLATE
    SHULGA, YM
    ROSCHUPKINA, OS
    DZHARDIMALIEVA, GI
    POMOGAILO, AD
    RUSSIAN CHEMICAL BULLETIN, 1993, 42 (09) : 1498 - 1501
  • [22] Reactivity of metal-containing monomers - 48. Thermal transformations of cobalt(II) maleate
    Rosenberg, AS
    Aleksandrova, EI
    Ivleva, NP
    Dzhardimalieva, GI
    Raevskii, AV
    Kolesova, OI
    Uflyand, IE
    Pomogailo, AD
    RUSSIAN CHEMICAL BULLETIN, 1998, 47 (02) : 259 - 264
  • [23] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .40. POLYMERIZATION TRANSFORMATIONS OF MONOMERS BASED ON VANADYL ALKOXY DERIVATIVES
    POMOGAILO, AD
    GOLUBEVA, ND
    RUSSIAN CHEMICAL BULLETIN, 1994, 43 (12) : 2020 - 2025
  • [24] Preparation and Reactivity of Metal-Containing Monomers. 78. Scandium-Containing Monomers And Polymers: Synthesis, Structure and Properties
    Dzhardimalieva, G. I.
    Semenov, S. A.
    Knerelman, E. I.
    Davydova, G. I.
    Kydralieva, K. A.
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2016, 26 (06) : 1441 - 1451
  • [25] Preparation and Reactivity of Metal-Containing Monomers. 78. Scandium-Containing Monomers And Polymers: Synthesis, Structure and Properties
    G. I. Dzhardimalieva
    S. A. Semenov
    E. I. Knerelman
    G. I. Davydova
    K. A. Kydralieva
    Journal of Inorganic and Organometallic Polymers and Materials, 2016, 26 : 1441 - 1451
  • [26] STUDY OF IMMOBILIZED CATALYSTS .24. CATALYSTS OBTAINED BY GRAFT-POLYMERIZATION OF METAL-CONTAINING MONOMERS ONTO POLYETHYLENE
    SAVOSTYANOV, VS
    POMOGAILO, AD
    PONOMAREV, AN
    KINETICS AND CATALYSIS, 1989, 30 (06) : 1230 - 1235
  • [27] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .17. SPATIAL AND ELECTRONIC-STRUCTURE OF COMPLEXES OF COBALT NITRATE AND CHLORIDE WITH ACRYLAMIDE
    UFLYAND, IE
    STARIKOV, AG
    SAVOSTYANOV, VS
    POMOGAILO, AD
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1990, 39 (06): : 1185 - 1189
  • [28] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .38. THERMODESTRUCTION OF POLYSTYRENE AND POLYACRYLONITRILE MODIFIED WITH TRIOSMIUM CARBONYL CLUSTER MONOMERS
    BRAVAYA, NM
    POMOGAILO, AD
    MAKSAKOV, VA
    KIRIN, VP
    BELOV, GP
    SOLOVIEVA, TI
    RUSSIAN CHEMICAL BULLETIN, 1994, 43 (03) : 381 - 386
  • [29] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .37. REDOX PROPERTIES AND ELECTROCHEMICAL POLYMERIZATION OF METHACRYLOYLACETONE AND ITS FE-III AND CU-II COMPLEXES
    GAVRILOV, AB
    MOVCHAN, TI
    POMOGAILO, AD
    RUSSIAN CHEMICAL BULLETIN, 1994, 43 (02) : 232 - 239
  • [30] Preparation and reactivity of metal-containing monomers .45. Determination of stability of monomeric metal chelates of substituted 6-heptene-1,3-diones in solutions
    Zheltvai, II
    Voloshanovskii, IS
    Butova, TD
    Pomogailo, AD
    RUSSIAN CHEMICAL BULLETIN, 1995, 44 (12) : 2299 - 2302
12345