ORGANOMETALLIC MACROCYCLE CHEMISTRY .4. SYNTHESIS AND REACTIONS OF [RUX(CS)(PPH(3))([9]ANES(3))] CLO4 (X=H, CL, SCN, SC(6)H(4)ME-4 - [9]ANES(3)=1,4,7-TRITHIACYCLONONANE)

被引：12

作者：

HECTOR, AL ^{[1
]}

HILL, AF ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 14期

关键词：

D O I：

10.1021/ic00118a029

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [RuCl2(OH2)(CS)(PPh(3))(2)] and [RuHCl(CS)(PPh(3))(3)] with 1,4,7-trithiacyclononane ([9]aneS(3)) provide the thiacrown complexes [RuX(CS)(PPh(3))([9]aneS(3))](+) (X = Cl, H; isolated as ClO4- salts). [RuCl(CS)(PPh(3))([9]aneS(3))]ClO4 reacts with potassium 4-toluenethiolate and potassium thiocyanate to provide the salts [RuX(CS)(PPh(3))([9]aneS(3))]ClO4 (X = SC(6)H(4)Me-4, SCN) but with sodium azide to provide [RuCl(NCS)(PPh(3))([9]aneS(3))].

引用

页码：3797 / 3800

页数：4

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