ORBITAL INTERACTIONS THROUGH-SPACE AND THROUGH SIGMA-BONDS

被引：0
|
作者：
BRODSKAYA, EI [1 ]
RATOVSKII, GV [1 ]
VORONKOV, MG [1 ]
机构：
[1] IRKUTSK STATE UNIV,INST PETR & CARBON SYNTHESIS,IRKUTSK 664033,RUSSIA
来源：
USPEKHI KHIMII | 1993年 / 62卷 / 10期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The present state of the now classic conception of orbital interactions between indirectly bonded lone pairs or pi-type groups is reported. Through space and through bond mechanisms of such interactions are discussed. The methods of the He(1) photoelectron, electron transmission, electronic absorption spectroscopy together with molecular orbital calculations are used to evaluate these interactions. The chemical consequenses of through bond orbital interactions are illustrated.
引用
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页码：975 / 990
页数：16
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