ORBITAL INTERACTIONS THROUGH-SPACE AND THROUGH SIGMA-BONDS

被引：0

作者：

BRODSKAYA, EI ^{[1
]}

RATOVSKII, GV ^{[1
]}

VORONKOV, MG ^{[1
]}

机构：

[1] IRKUTSK STATE UNIV,INST PETR & CARBON SYNTHESIS,IRKUTSK 664033,RUSSIA

来源：

USPEKHI KHIMII | 1993年 / 62卷 / 10期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present state of the now classic conception of orbital interactions between indirectly bonded lone pairs or pi-type groups is reported. Through space and through bond mechanisms of such interactions are discussed. The methods of the He(1) photoelectron, electron transmission, electronic absorption spectroscopy together with molecular orbital calculations are used to evaluate these interactions. The chemical consequenses of through bond orbital interactions are illustrated.

引用

页码：975 / 990

页数：16

共 50 条

[1] ELECTROCHEMICAL EVIDENCE FOR THROUGH-SPACE ORBITAL INTERACTIONS IN SPIROMETHANOFULLERENES
EIERMANN, M
HADDON, RC
KNIGHT, B
LI, QC
MAGGINI, M
MARTIN, N
OHNO, T
PRATO, M
SUZUKI, T
WUDL, F
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (15): : 1591 - 1594
[2] A PMO APPROACH TO ORBITAL INTERACTIONS THROUGH SPACE AND THROUGH BONDS
LEE, I
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1982, 3 (04) : 140 - 144
[3] Through-space and through-bridge interactions in the correlation analysis of chemical bonds
Szczepanik, Dariusz W.
Mrozek, Janusz
COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2013, 1026 : 72 - 77
[4] Through-Space Interactions in Clusteroluminescence
Zhang, Haoke
Tang, Ben Zhong
JACS AU, 2021, 1 (11): : 1805 - 1814
[5] THROUGH-SPACE INTERACTIONS IN SPIRENES
BOERTH, DW
MORAIS, J
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1989, 52 (3-4): : 257 - 269
[6] Strong through-space interactions
Dandliker, P.J.
Diederich, C.B.
Gross, M.
Knobler, C.B.
Louatt, A.
Sanford, E.M.
Angewandte Chemie (International Edition in English), 1994, 33 (17): : 1739 - 1742
[7] Through-space and through-bridge components of chemical bonds
Roman F. Nalewajski
Journal of Mathematical Chemistry, 2011, 49 : 371 - 392
[8] Through-space and through-bridge components of chemical bonds
Nalewajski, Roman F.
JOURNAL OF MATHEMATICAL CHEMISTRY, 2011, 49 (02) : 371 - 392
[9] ON THE PRESENCE OF EXTREMELY SHORT H...H NON-BONDED DISTANCES, AND ORBITAL INTERACTIONS THROUGH 8 SIGMA-BONDS OR THROUGH 2 METHYLENE GROUPS IN TETRAMETHANONAPHTHACENES
JORGENSEN, FS
PADDONROW, MN
TETRAHEDRON LETTERS, 1983, 24 (48) : 5415 - 5418
[10] SPECTROSCOPIC EVIDENCE OF THE CHARGE-TRANSFER THROUGH SIGMA-BONDS IN NITROZAADAMANTANES
AGASHKIN, OV
SHUSTOVA, LM
KOSMAKOV, VA
KUZNETSOV, AI
UNKOVSKII, BV
DOKLADY AKADEMII NAUK SSSR, 1988, 303 (02): : 373 - 376

← 1 2 3 4 5 →