RHODIUM(I) AND IRIDIUM(I) COMPLEXES OF PH2P(S)CH2P(S)PH2, BIS(DIPHENYLPHOSPHINO)METHANE DISULFIDE

被引：23
|
作者：
ABBASSIOUN, MS
CHALONER, PA
CLAVER, C
HITCHCOCK, PB
MASDEU, AM
RUIZ, A
SABALLS, T
机构：
[1] FAC QUIM TARRAGONA, DEPT QUIM, PL IMPERIAL TARRACCO 1, E-43005 TARRAGONA, SPAIN
[2] UNIV SUSSEX, SCH CHEM & MOLEC SCI, BRIGHTON BN1 9QJ, E SUSSEX, ENGLAND
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 403卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(91)83104-C
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rhodium(I) and iridium(I) complexes of the ligand bis(diphenylphosphino)methane disulphide (dp-pmS2) have been prepared and characterised. The structures of [Rh(dppmS2)(cod)][C1O4] and [Rh(dppmS2)(CO)2][C1O4] were established in diffraction studies, the latter complex adopting an interesting pseudo-dimeric structure in the solid state.
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页码：229 / 241
页数：13
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