SYNTHESIS OF NONESTER PYRETHROIDS HAVING A 1-FLUORO-1-METHYLETHYL GROUP USING 1,2-MIGRATION OF AN ARYL GROUP

被引：2
|
作者：
UNEME, H
OKADA, Y
机构：
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 09期
关键词：
D O I：
10.1246/bcsj.65.2401
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
When 1,4-diaryl-4-methyl-1,3-pentanediol was treated with diethylaminosulfur trifluoride to introduce fluorine atoms into the central link, 1,2-aryl group migration products which have a 1-fluoro-1-methylethyl group were obtained as two diastereomers. Utilizing this migration, some non-ester pyrethroids possessing a 1-fluoro-1-methylethyl group were prepared. The reactivity of other fluorinating reagents is also discussed.
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页码：2401 / 2410
页数：10
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