A MATHEMATICAL-MODEL DESCRIBING THE ARI AUTOCIRCULATION REACTOR FOR LOW-TEMPERATURE CONVERSION OF H2S INTO SULFUR

A Prototype ''autocirculation''-type reactor has been designed and constructed at the N.I.O.C. Research Institute, Tehran and a mathematical model describing the concentration versus time profile subsequently developed. The model encompasses mass transfer considerations and kinetic studies of the regeneration reaction. For this purpose, the rate equation for iron complex oxidation, proposed by Japanese researchers, was modified and a new rate equation presented. This rate equation has been widely used in the above mentioned mathematical model. With this model, the vessel volume for a time-dependent H2S feed has been calculated for a ''ZDDP'' production unit.