MAGNETIC-FIELD EFFECT ON THE DYNAMIC BEHAVIOR OF A RADICAL PAIR INVOLVING AN SN-CENTERED RADICAL

被引：7
|
作者：
WAKASA, M
HAYASHI, H
机构：
[1] Molecular Photochemistry Laboratory, The Institute of Physical and Chemical Research (RIKEN), Wako, Saitama
来源：
CHEMICAL PHYSICS LETTERS | 1994年 / 229卷 / 1-2期
关键词：
D O I：
10.1016/0009-2614(94)01014-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The photoreduction of xanthone with triethyltinhydride in a sodium dodecylsulfate solution was investigated with the aid of a time-resolved ESR and a nanosecond laser flash photolysis. Upon irradiation of xanthone with triethyltinhydride, the hydrogen abstraction occurred and the ketyl-type and cyclohexadienyl-type radicals were observed by CIDEP spectra. The escaped xanthone ketyl radical increased with increasing magnetic field strength up to 1.29 T. The observed magnetic filed effects can be interpreted by a combination of the hyperfine coupling and the relaxation mechanisms in the case of a triplet radical pair.
引用
收藏
页码：122 / 126
页数：5
相关论文
共 50 条
  • [21] Effect of magnetic field on the biological clock through the radical pair mechanism
    Abeyrathne, Chathurika D.
    Halgamuge, Malka N.
    Farrell, Peter M.
    World Academy of Science, Engineering and Technology, 2010, 64 : 141 - 146
  • [22] Effect of magnetic field on the biological clock through the radical pair mechanism
    Abeyrathne, Chathurika D.
    Halgamuge, Malka N.
    Farrell, Peter M.
    World Academy of Science, Engineering and Technology, 2010, 40 : 141 - 146
  • [23] On the anisotropic weak magnetic field effect in radical-pair reactions
    Luo, Jiate
    JOURNAL OF CHEMICAL PHYSICS, 2023, 158 (23):
  • [24] MAGNETIC-FIELD EFFECTS ON RADICAL PROCESSES IN BIOMEMBRANES
    KADNIKOV, OG
    ZALJUBOVSKIJ, II
    KOBIZSKOJ, VI
    VITOVTOVA, TI
    DOPOVIDI AKADEMII NAUK UKRAINSKOI RSR SERIYA B-GEOLOGICHNI KHIMICHNI TA BIOLOGICHNI NAUKI, 1978, (10): : 927 - 930
  • [25] MAGNETIC-FIELD EFFECTS ON RADICAL PAIR RECOMBINATION IN LIQUIDS - NONADIABATIC TRANSITIONS AT LOW MAGNETIC-FIELDS
    SHUSHIN, AI
    CHEMICAL PHYSICS LETTERS, 1995, 237 (1-2) : 177 - 182
  • [26] MAGNETIC-FIELD EFFECT ON COMBUSTION - EMISSION INTENSITY OF THE OH RADICAL FLAMES
    HAYASHI, H
    NIPPON KAGAKU KAISHI, 1984, (11) : 1753 - 1758
  • [27] EFFECT OF A MAGNETIC-FIELD ON THE KINETICS OF RADICAL DISPROPORTIONATION IN VISCOUS-LIQUIDS
    MARGULIS, LA
    KHUDYAKOV, IV
    KUZMIN, VA
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1985, 34 (04): : 874 - 874
  • [28] CIDNP STUDY OF PHOTOINDUCED RADICAL REACTION - EFFECT OF APPLIED MAGNETIC-FIELD
    MARUYAMA, K
    HAYAMI, J
    OTSUKI, T
    CHEMISTRY LETTERS, 1983, (06) : 845 - 846
  • [29] DEPENDENCE OF THE YIELD OF A RADICAL-PAIR REACTION IN THE SOLID-STATE ON ORIENTATION IN A MAGNETIC-FIELD
    BOXER, SG
    CHIDSEY, CED
    ROELOFS, MG
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (09) : 2674 - 2675
  • [30] MAGNETIC-FIELD EFFECTS IN RADICAL PAIR RECOMBINATION .1. CIDNP AND CIDEP IN GEMINATE RECOMBINATION
    SHUSHIN, AI
    CHEMICAL PHYSICS, 1990, 144 (02) : 201 - 222
12345