1,1-DICHLOROETHANE CHLORINATION IN 1,2,4-TRICHLOROBENZENE MEDIUM

被引：0
|
作者：
AVERYANOV, VA
PETROVA, GN
SAIGANOVA, LN
机构：
来源：
KHIMICHESKAYA PROMYSHLENNOST | 1982年 / 12期
关键词：
SOLVENTS - Electronic Properties;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A study is made of the free-radical chlorination of 1,1-dichloroethane in a 1,2,4-trichlorobenzene medium in a wide range of temperatures ( minus 20 to plus 50 degree C) and solvent concentrations (0 to 6 mol/liter). The selective action of the solvent is interpreted in terms of a mechanism including attack of C-H bonds in 1,1-dichloroethane by chlorine atoms and aromatic II-complexes. An equation for determining the selectivity of the investigated process is obtained. The parameters of the equation are discussed from the standpoint of the electron-donor properties of the solvent.
引用
收藏
页码：721 / 722
页数：2
相关论文
共 50 条
  • [31] In silico feasibility of novel biodegradation pathways for 1,2,4-trichlorobenzene
    Finley, Stacey D.
    Broadbelt, Linda J.
    Hatzimanikatis, Vassily
    BMC SYSTEMS BIOLOGY, 2010, 4
  • [32] PHOTOMETRIC-DETERMINATION OF TETRATHIOTETRACENE IN THE 1,2,4-TRICHLOROBENZENE SOLUTION
    AVRAMENKO, NV
    KISELIOVA, NA
    DEMIDOVA, AL
    VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 2 KHIMIYA, 1991, 32 (02): : 134 - 136
  • [33] THE MOLECULAR STRUCTURE OF 1,1-DICHLOROETHANE BY ELECTRON DIFFRACTION
    DANFORD, MD
    LIVINGSTON, RL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (16) : 4157 - 4159
  • [34] ORGANOMERCURY COMPOUNDS .25. THE MERCURATION OF 1,2,4-TRICHLOROBENZENE
    DEACON, GB
    TAYLOR, BSF
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1981, 34 (02) : 301 - 312
  • [35] GPC EFFECT OF TEMPERATURE ON ELUTION BEHAVIOR IN 1,2,4-TRICHLOROBENZENE
    BERGMANN, JG
    DUFFY, LJ
    JOURNAL OF CHROMATOGRAPHY, 1972, 67 (02): : D82 - &
  • [36] Relations between compression and thermal contraction in 1,2,4-trichlorobenzene and melting of trichlorobenzene isomers
    Bujak, Maciej
    Podsiadlo, Marcin
    Katrusiak, Andrzej
    CRYSTENGCOMM, 2015, 17 (18): : 3446 - 3451
  • [37] Silicon Alleviates the Stress of 1,2,4-Trichlorobenzene on Rice Seedlings
    Feiyu Yan
    Linqing Zhang
    Le Liu
    Xinhai Liu
    Fang Wang
    Zhiwei Huang
    Hongliang Zhao
    Guoliang Zhang
    Silicon, 2023, 15 : 7371 - 7381
  • [38] Exogenous silicon enhances resistance to 1,2,4-trichlorobenzene in rice
    Niu, Yuan
    Liu, Le
    Wang, Fang
    Liu, Xinhai
    Huang, Zhiwei
    Zhao, Hongliang
    Qi, Bo
    Zhang, Guoliang
    SCIENCE OF THE TOTAL ENVIRONMENT, 2022, 845
  • [39] THERMAL REACTION OF ORGANOCHLOROSILICON HYDRIDES AND TRICHLOROSILANE WITH 1,2,4-TRICHLOROBENZENE
    CHERNYSH.EA
    CHARSKAY.BA
    VOROBEV, VD
    ZHURNAL PRIKLADNOI KHIMII, 1971, 44 (04) : 899 - +
  • [40] MATERNAL HEPATIC AND EMBRYONIC EFFECTS OF 1,2,4-TRICHLOROBENZENE IN THE RAT
    KITCHIN, KT
    EBRON, MT
    ENVIRONMENTAL RESEARCH, 1983, 31 (02) : 362 - 373
12345