1,1-DICHLOROETHANE CHLORINATION IN 1,2,4-TRICHLOROBENZENE MEDIUM

被引：0
|
作者：
AVERYANOV, VA
PETROVA, GN
SAIGANOVA, LN
机构：
来源：
KHIMICHESKAYA PROMYSHLENNOST | 1982年 / 12期
关键词：
SOLVENTS - Electronic Properties;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A study is made of the free-radical chlorination of 1,1-dichloroethane in a 1,2,4-trichlorobenzene medium in a wide range of temperatures ( minus 20 to plus 50 degree C) and solvent concentrations (0 to 6 mol/liter). The selective action of the solvent is interpreted in terms of a mechanism including attack of C-H bonds in 1,1-dichloroethane by chlorine atoms and aromatic II-complexes. An equation for determining the selectivity of the investigated process is obtained. The parameters of the equation are discussed from the standpoint of the electron-donor properties of the solvent.
引用
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页码：721 / 722
页数：2
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