3-COMPONENTS SYNTHESIS OF VINYL CYCLOPROPANE CARBOXYLIC-ACIDS

被引：0
|
作者：
KRIEF, A
DUMONT, W
PROVINS, L
机构：
来源：
SYNLETT | 1995年 / 01期
关键词：
CHRYSANTHEMIC ACID; ALLYL STANNANES; ALLYL SILANES; GAMMA-HYDROXYALKYL;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
gamma-Hydroxyalkyl allyl stannanes and -silanes lead selectively to a large variety of products depending upon the reagent used (BF3.0Et(2) or thionyl chloride). Suitable combination allows the synthesis of vinyl cyclopropane carboxylic acids including chrysanthemic acid, the constituent of the most potent commercially available pyrethroid insecticide.
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页码：121 / 122
页数：2
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