SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF OXOTRIMESITYLIRIDIUM(V)

被引：118
|
作者：
HAYMOTHERWELL, RS
WILKINSON, G
HUSSAINBATES, B
HURSTHOUSE, MB
机构：
[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,JOHNSON MATTHEY LAB,LONDON SW7 2AY,ENGLAND
[2] UNIV WALES CARDIFF,DEPT CHEM & APPL CHEM,CARDIFF CF1 3TB,WALES
来源：
POLYHEDRON | 1993年 / 12卷 / 16期
关键词：
D O I：
10.1016/S0277-5387(00)81474-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The interaction of trimesityliridium(III) with trimethylamine oxide gives quantitative yields of the green iridium(V) complex Ir(O)(mes)3, whose X-ray crystal structure has been determined. The oxo compound is also obtained by interaction of dioxygen with Ir(mes)3 and Ir(mes)4. A similar oxo species has also been obtained from Ir(2,6-Me2C6H3)4. The molecular structure of Ir(O)(mes)3 is distorted tetrahedral with Ir=O and Ir-C bond lengths of 1.725(9) and 1.989-2.034(13) angstrom, respectively.
引用
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页码：2009 / 2012
页数：4
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