CRYSTAL AND MOLECULAR-STRUCTURE OF AN OLIGOMERIC-1/2 COMPLEX OF COPPER(II) AZIDE WITH 4-METHYLPYRIDINE

被引：21
|
作者：
GOHER, MAS [1 ]
MAUTNER, FA [1 ]
机构：
[1] GRAZ TECH UNIV,INST PHYS & THEORET CHEM,A-8010 GRAZ,AUSTRIA
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 1992年 / 27卷 / 06期
关键词：
D O I：
10.1002/crat.2170270614
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A 1:2 complex of copper(II) azide with 4-methylpyridine has been synthesized and the crystal structure has been determined by X-ray methods. The compound crystallizes in space group P2(1)/a with a = 11.062(3), b = 19.310(6), c = 20.547(5) angstrom, beta = 90.83(2)-degrees, V = 4389(1) angstrom3, Z = 12 and R = 0.048 for 959 observed MoKalpha data. The structure is built up by oligomeric edge-sharing chains of polyhedra. With the exception of a single coordinated azido group, all other azido ligands serve to bridge neighbouring copper centers [at Cu - N bond distances of 1.94(2) to 2.76(2) angstrom] in the mu(1, 1) fashion.
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页码：817 / 823
页数：7
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