INVESTIGATION OF THE MAGNETIC-PROPERTIES OF THE GD1-XERX ALLOY SYSTEM IN THE X-LESS-THAN-0.62 COMPOSITION RANGE

The magnetic properties of the Gd-Er system (with erbium concentrations ranging from 0 to 62 at%) were investigated at temperatures between 4.2 and 350 K under external magnetic fields up to 1 T. The results show that, similar to other rare-earth systems, simple ferromagnetism prevails for concentrations with a de Gennes factor G higher than about 11.5 (approximate to 30 at % Er) while complex magnetic structures are present for higher Er concentrations (G less than or equal to 11.5). The magnetic transition temperature decreases with increasing Er content, showing good agreement with phenomenological expectations. In the paramagnetic region, the Curie constant of the alloy corresponds to the linear combination of the constituent elements' contribution, thus proving that both Gd and Er maintain. their individual magnetic moments. From magnetization data below the transition, the change in magnetic entropy for a 1 T field was calculated and this showed distinct differences between ferromagnetic-paramagnetic transitions and antiferromagnetic-paramagnetic transitions. The Landau theory of second-order phase transitions can be well applied for evaluating the thermodynamic transition temperature and the specific heat anomaly in the ferromagnetic alloys but it fails for the more complex structures if the applied field is not far higher than the critical field. The magnetic entropy change displays well defined peaks at the transition temperature for both ferromagnetic and antiferromagnetic alloys. There is an indication that the spin-reorientation transition occurring in alloys with higher Er concentrations is also coupled with significant magnetic entropy changes.