NONEQUILIBRIUM GLOW-DISCHARGE FLUORINATION OF POLYMER SURFACES

被引：65
|
作者：
HOPKINS, J [1 ]
BADYAL, JPS [1 ]
机构：
[1] UNIV DURHAM,DEPT CHEM,SCI LABS,DURHAM DH1 3LE,ENGLAND
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 12期
关键词：
D O I：
10.1021/j100012a056
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
CF4 plasma treatment of a range of polymers (polyethylene, polypropylene, polyisoprene, polystyrene, polyether ether ketone, polyethylene terephthalate, polycarbonate, polysulfone, and polyether sulfone) has been investigated by X-ray photoelectron spectroscopy (XPS). A correlation is found to exist between the level of fluorine incorporation into the surface and the chemical structure of the parent polymer. This experimental observation can be rationalized on a theoretical basis in terms of results obtained from extended Huckel molecular orbital calculations.
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页码：4261 / 4264
页数：4
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