STUDIES ON THERMAL-DEGRADATION OF CELLULOSE AND CELLULOSE PHOSPHORAMIDES

被引：24
|
作者：
KAUR, B
GUR, IS
BHATNAGAR, HL
机构：
[1] Kurukshetra Univ, Kurukshetra, India, Kurukshetra Univ, Kurukshetra, India
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 1986年 / 31卷 / 02期
关键词：
CELLULOSE DERIVATIVES - Pyrolysis - CHEMICAL REACTIONS - Thermodynamics - FLAME RETARDANTS - Testing;
D O I：
10.1002/app.1986.070310231
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Reaction of cellulose with hexamethylphosphoric acid triamide has been investigated under various physical conditions. Dimethylamine hydrochloride was found to be an efficient catalyst for the system. The thermal degradation of cellulose and its phosphoramide products in air was studied from ambient temperature to 500 degree C. The data were processed for the various thermodynamic parameters. A mechanism for the thermal degradation of cellulose phosphoramide has been proposed.
引用
收藏
页码：667 / 683
页数：17
相关论文
共 50 条
  • [31] Thermal degradation of cellulose and cellulose esters
    Huang, MR
    Li, XG
    JOURNAL OF APPLIED POLYMER SCIENCE, 1998, 68 (02) : 293 - 304
  • [32] PREPARATIVE ISOLATION OF OLIGOMERS WITH A TERMINAL ANHYDROSUGAR UNIT BY THERMAL-DEGRADATION OF CHITIN AND CELLULOSE
    KOLL, P
    BORCHERS, G
    METZGER, JO
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1990, 17 (04) : 319 - 327
  • [33] A KINETIC-STUDY OF THE THERMAL-DEGRADATION OF CELLULOSE AND SOME RELATED MODEL COMPOUNDS
    JAIN, RK
    LAL, K
    BHATNAGAR, HL
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1984, 23 (10): : 828 - 833
  • [34] Studies on thermal degradation of cellulose and its thiophosphorylated derivatives
    Trehan, R
    Kad, GL
    Lal, K
    Singh, R
    JOURNAL OF POLYMER MATERIALS, 1995, 12 (03): : 183 - 190
  • [35] STUDY ON THE THERMAL-DEGRADATION OF COTTON CELLULOSE AMMONIUM PHOSPHATE AND ITS METAL-COMPLEXES
    TIAN, CM
    GUO, HZ
    ZHANG, HY
    XU, JZ
    SHI, JR
    THERMOCHIMICA ACTA, 1995, 253 : 243 - 251
  • [36] STUDIES ON THE THERMAL-DEGRADATION OF CELLOBIOSE
    KALA, C
    GUR, IS
    BHATNAGAR, HL
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1979, 56 (09) : 890 - 894
  • [37] On the thermal degradation of cellulose allomorphs
    Ciolacu, Diana
    Popa, Valentin I.
    CELLULOSE CHEMISTRY AND TECHNOLOGY, 2006, 40 (06): : 445 - 449
  • [38] Thermal Degradation of Cotton Cellulose
    C. M. Tian
    Z. H. Shi
    H. Y. Zhang
    J. Z. Xu
    J. R. Shi
    H. Z. Guo
    Journal of Thermal Analysis and Calorimetry, 1999, 55 : 93 - 98
  • [39] Thermal degradation of cotton cellulose
    Tian, CM
    Sii, ZH
    Zhang, NY
    Xu, JZ
    Shi, JR
    Guo, HZ
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 1999, 55 (01): : 93 - 98
  • [40] THERMAL DEGRADATION OF WOOD AND CELLULOSE
    STAMM, AJ
    INDUSTRIAL AND ENGINEERING CHEMISTRY, 1956, 48 (03): : 413 - 417
12345